Building Web Applications with ASP.NET 3.5 and Microsoft Visual Web Developer 2008

Refer this link,

http://www.asp.net/learn/videos/#VisualWebDeveloper

Here list of video series are available, it will help you develop a functional understanding of using Microsoft’s free IDE for web application developer (Visual Web Developer) to build ASP.NET 2.0 & 3.5 web applications. Microsoft’s Joe Stagner demonstrates not only how to use the “VWD” IDE but explains what’s happening behind the scenes and offers guidance on best practices.

have a look at this site, hope it helps everyone.